What to use to capture PS1 Game screenshots?

What bios are you using (though I doubt that is the problem).

Is it a specific error screen from ePSXe, or it just refuses to boot. If so, then can you post the error screen it gives?

 

It's bios 1001. No error screen I was told (only a black screen after you choose your characters). I'll let you know when I get the game in the mail this week.